Asymmetric Organocatalysis: From Biomimetic Concepts to Applications in Asymmetric Synthesis

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Asymmetric catalysis represents still one of the major challenges in modern organic chemistry. Besides the well-established asymmetric metal-complex-catalysed syntheses and biocatalysis, the use of "pure" organic catalysts turned out to be an additional efficient tool for the synthesis of chiral building blocks. In this handbook, the experienced authors from academia and industry provide the first overview of the important use of such metal-free organic catalysts in organic chemistry. With its comprehensive description of numerous reaction types, e.g., nucleophilic substitution and addition reactions as well as cycloadditions and redox reactions, this book targets organic chemists working in industry and academia, and deserves a place in every laboratory.

Catalysis in Asymmetric Synthesis (Post-Graduate Chemistry Series)

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Catalysis in Asymmetric Synthesis (Post-Graduate Chemistry Series)
Jonathan Williams
Manufacturer: Blackwell Publishers
ProductGroup: Book
Binding: Hardcover

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Catalytic Asymmetric Synthesis, Second Edition

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Catalytic Asymmetric Synthesis, Second Edition

Manufacturer: Wiley-VCH
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Binding: Hardcover

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ASIN: 0471298050

Book Description

From the reviews of the First Edition . . .

"An excellent text . . . will no doubt provide the benchmark for comparative works for many years."
—Journal of the American Chemical Society

"A resounding success . . . the definitive current summaries on their respective subjects."
—Synthesis

Since this important work was first published in 1993, the field of catalytic asymmetric synthesis has grown explosively, spawning effective new methods for obtaining enantiomerically pure compounds on a large scale and stimulating new applications in diverse fields-from medicine to materials science. Catalytic Asymmetric Synthesis, Second Edition addresses these rapid changes through new or substantially revised contributions from highly recognized world leaders in the field. It presents detailed accounts of the most important catalytic asymmetric reactions known today, discusses recent advances, and retains from the previous edition essential and intriguing information on the initial development of certain processes. An excellent working resource for academic researchers and industrial chemists alike, the Second Edition features:

Contributions from Noyori, Sharpless, Kagan, Trost, Overman, Shibasaki, Doyle, Okamoto, Bolm, Carreira, and many other internationally renowned authorities
New chapters on asymmetric carbometallations, asymmetric amplification and autocatalysis, and asymmetric polymerization
Extended coverage of asymmetric carbene reactions, including asymmetric intramolecular carbene insertion to C-H bonds as well as asymmetric dihydroxylation and aminohydroxylation
Extended coverage of asymmetric carbon-carbon bond-forming reactions and applications
An appendix listing all chiral ligands in the book

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From the reviews of the First Edition . . .

"An excellent text . . . will no doubt provide the benchmark for comparative works for many years."-Journal of the American Chemical Society

"A resounding success . . . the definitive current summaries on their respective subjects."-Synthesis

Since this important work was first published in 1993, the field of catalytic asymmetric synthesis has grown explosively, spawning effective new methods for obtaining enantiomerically pure compounds on a large scale and stimulating new applications in diverse fields-from medicine to materials science. Catalytic Asymmetric Synthesis, Second Edition addresses these rapid changes through new or substantially revised contributions from highly recognized world leaders in the field. It presents detailed accounts of the most important catalytic asymmetric reactions known today, discusses recent advances, and retains from the previous edition essential and intriguing information on the initial development of certain processes. An excellent working resource for academic researchers and industrial chemists alike, the Second Edition features:
* Contributions from Noyori, Sharpless, Kagan, Trost, Overman, Shibasaki, Doyle, Okamoto, Bolm, Carreira, and many other internationally renowned authorities
* New chapters on asymmetric carbometallations, asymmetric amplification and autocatalysis, and asymmetric polymerization
* Extended coverage of asymmetric carbene reactions, including asymmetric intramolecular carbene insertion to C-H bonds as well as asymmetric dihydroxylation and aminohydroxylation
* Extended coverage of asymmetric carbon-carbon bond-forming reactions and applications
* An appendix listing all chiral ligands in the book

Asymmetric Catalysis In Organic Synthesis (Baker Lecture Series)

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Asymmetric Catalysis In Organic Synthesis (Baker Lecture Series)
Ryoji Noyori
Manufacturer: Wiley-Interscience
ProductGroup: Book
Binding: Hardcover

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ASIN: 0471572675

Book Description

Deals with basic principles of asymmetric catalysis focusing on its synthetic significance. Covers homogeneous asymmetric hydrogenation, asymmetric catalysis via chiral metal complexes, heterogeneous catalysis and non-organometallic catalysis. The collection of a range of stereoselective reactions illustrate various strategies and methodologies as well as their general utility.

Asymmetric Catalysis on Industrial Scale: Challenges, Approaches and Solutions (Chemistry)

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Asymmetric Catalysis on Industrial Scale: Challenges, Approaches and Solutions (Chemistry)

Manufacturer: Wiley-VCH
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Binding: Hardcover

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ASIN: 3527306315

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Edited by two of the experts in the field, the central aim is to show organic chemists working in process development that enantioselective catalysis is suitable for the large-scale production of enantioenriched intermediates. In so doing, it is equally a source of information and inspiration for academic research, and, with its contribution by Noble prizewinner W. S. Knowles, will also heighten the status of industrial catalyst specialists working in the exciting field of enantioselective catalysis.

Book Description

The second supplement to the three volume reference work Comprehensive Asymmetric Catalysis critically reviews new developments to the hottest topics in the field written by recognised experts. Seven chapters which are already in the major reference work have been supplemented and additionally a new chapter on Aminohydroxylation of Carbon-Carbon Double Bonds has been included. Thus, the state of the art in this area is now re-established. Together with the basic three volume book set and Supplement 1 it is not only the principal reference source for synthetic organic chemists, but also for all scientific researchers who use chiral compounds in their work (for example, in biochemical investigations and molecular medicine) as well as for pharmaceutical chemists and other industrial researchers who prepare chiral compounds.

Comprehensive Asymmetric Catalysis: Supplement 1

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Comprehensive Asymmetric Catalysis: Supplement 1

Manufacturer: Springer
ProductGroup: Book
Binding: Hardcover

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The first supplement to the three volume reference work "Comprehensive Asymmetric Catalysis" critically reviews new developments to the hottest topics in the field written by recognised experts. Eleven chapters which are already in the major reference work have been supplemented and additionally five new chapters have been included. Thus the state-of-the art in this area is now re-established. Together with the basic three volume book set this supplement is not only the principal reference source for synthetic organic chemists, but also for all scientific researchers who use chiral compounds in their work (for example, in biochemical investigations and molecular medicine) as well as for pharmaceutical chemists and other industrial researchers who prepare chiral compounds.

Heterogeneous Enantioselective Hydrogenation: Theory and Practice (Catalysis by Metal Complexes)

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Heterogeneous Enantioselective Hydrogenation: Theory and Practice (Catalysis by Metal Complexes)
Evgenii Klabunovskii , Gerard V. Smith , and Ágnes Zsigmond
Manufacturer: Springer
ProductGroup: Book
Binding: Hardcover

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ASIN: 1402042949

Book Description

Heterogeneous Enantioselective Hydrogenation: Theory and Practice reviews the development of enantioselective hydrogenation reaction catalysts. It looks at the first relatively ineffective catalysts right through to modern highly effective enantioselective catalytic systems, comparable in their efficiency to chiral metal complexes and enzymatic systems. The book begins with a summary of the first work on heterogeneous metal catalysts, which showed only the principal possibilities of enantioselective reactions. It then elaborates on metal catalysts which have enantioselectivities close to 100%. Finally, the practical utilization of chiral catalytic systems in processes of hydrogenation is described. The alpha- and beta-hydroxy carboxylic acid esters produced are precursors for manufacturing many synthones used for medicines as well as for monomers used for biodegradable polyesters, both of which have important practical applications.

The volume summarizes more than 800 scientific papers in the field of enantioselective catalytic hydrogenation reactions, mainly those using heterogeneous metal catalysts. It provides detailed explanations of special techniques for the preparation of effective dissymmetric catalysts which provide highly efficient catalytic systems. This book differs from previous publications by virtue of the recommendations for the practical utilization of recently described preparations of metal catalysts.

This book will be an invaluable resource to catalysis researchers as well as to those utilizing the technology.

Methodologies in Asymmetric Catalysis (Acs Symposium Series)

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Methodologies in Asymmetric Catalysis (Acs Symposium Series)

Manufacturer: An American Chemical Society Publication
ProductGroup: Book
Binding: Hardcover

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ASIN: 0841238359

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Methodologies in Asymmetric Catalysis brings together leading scientists who have made major contributions to the field of asymmetric catalysis. This book assembles several new methodologies that are interdisciplinary by nature, incorporating organic synthesis, coordination chemistry, auto-catalysis, homogeneous and heterogeneous catalysis, kinetics and mechanism, etc. Thirteen chapters are included. Methodologies in Asymmetric Catalysis covers areas of rapid progress and industrial importance. Each chapter in the book provides a new methodology for chiral transformation via asymmetric catalysis. This field has been an important topic of research for scientists in both industry and academia over the past 30 years. It presents a highly fertile field for the development of pharmaceuticals and fine chemicals. Three scientists were awarded the Nobel Prize in Chemistry in 2001 for their work in asymmetric catalysis.

Phosphorus Ligands in Asymmetric Catalysis: Synthesis and Applications

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Phosphorus Ligands in Asymmetric Catalysis: Synthesis and Applications

Manufacturer: Wiley-VCH
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Binding: Hardcover

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The ultimate standard reference work on phosphorus in catalysis in three volumes. Clearly divided into substance classes the reader gains an excellent introduction to the multitude of applications, backed by examples of optimal solutions.

Book Description

This book presents the concepts needed to deal with self-organizing complex systems from a unifying point of view that uses macroscopic data. The various meanings of the concept "information" are discussed and a general formulation of the maximum information (entropy) principle is used. With the aid of results from synergetics, adequate objective constraints for a large class of self-organizing systems are formulated and examples are given from physics, life and computer science. The relationship to chaos theory is examined and it is further shown that, based on possibly scarce and noisy data, unbiased guesses about processes of complex systems can be made and the underlying deterministic and random forces determined. This allows for probabilistic predictions of processes, with applications to numerous fields in science, technology, medicine and economics. The extensions of the third edition are essentially devoted to an introduction to the meaning of information in the quantum context. Indeed, quantum information science and technology is presently one of the most active fields of research at the interface of physics, technology and information sciences and has already established itself as one of the major future technologies for processing and communicating information on any scale.

This book addresses graduate students and nonspecialist researchers wishing to get acquainted with the concept of information from a scientific perspective in more depth. It is suitable as a textbook for advanced courses or for self-study.

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physics approach.......2000-09-01

Self-Organization is not the function given to a neural net (although they have taken it) used for pattern recognition, nor is it a cult somewhere in Germany. After following Haken's work for 6-8 years it is good to see a summary of sorts. Haken was working with self-organizing similarities in the 80's when unification ideas were rampant. Haken uses this same analogy by equating the basic form to stochastic differential equations. It is somewhat easier to approach the differential equation as a dynamical system driven by random vector fields of which the Ito form (stuff Kalman filters are made of) is a special case. Without going into martingales Brownian motion ergodic theorems of Markovian processes Haken does give a convincing argument for what he terms MIP (max. information principle) and information gain in the system. Linguistically converted this means that the process may be likened to a diffusion process with thermodynamic stuff. This paves the way for the transfer of information from one organization structure diffusion (in the wave) front to another. It seems to me, however, that a much simpler proof would be; show the parallel between Haken's basic form and the Lax form of an evolution equation. Establish relationship to Hirota's derivatives. Usually represented and manifested as the Korteweg-deVrie equations the polynomials groups describing the equation easily convert to Hiroto derivatives. Show fundamental relationship to n-solitons and vertex operators, establish relationship to Heisenberg and Clifford algebras, show Fock representation of Bosons using Maya diagrams, show Boson-Fermion correspondence. Complex variables, infinite dimensional algebras, Fermions, and Bosons; The principle of superposition does not apply to non-linear waves, despite that there exists exact solutions containing an arbitrary number of parameters suggesting an infinite dimensional transformation group acting on spaces of solutions of integrable systems (Reaction-diffusion as one type shock waves as another). Because of this self-symmetry in scales of complex polynomials, transformational methods work well. If waves are information densities and an increase in entropy is an increase of information Hiroto's derivatives would give the mathematical link showing the degrees of information transfer between types of diffusion front (waves) and another. The similarity of scales, the repeating nature, then transfer of one wave front (diffusion) through another without annihilation.

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